The thing about titanium is that although they're lighter, they can't sustain a heavy firing schedule so it's best to keep the temp under 800*F. I haven't read of anyone having longevity issues with a Ti can otherwise. I don't understand how/why a Ti can would inherently be more accurate compared to something made from another material other than having less weight hanging at the end of the barrel.
Best bet would be to talk to long range shooters about the Dead Air Ti and see how they like it. You said accuracy is the most important so it's hard to recommend them because they only came out recently. The price is attractive vs others though.
People start out wanting to do shooting as a hobby and it ends up their hobby is actually buying and operating expensive tools. Doesn't make sense when you think about it.
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