WC846 was what the original 5.56mm and 7.62mm were loaded with. Around 1967, it was noted that certain lots of WC846 were causing malfunctions in the endurance portion of the M16 acceptance tests. It was speculated that excessive calcium carbonate was being deposited in the gas tube. A test of two lots of WC846, one with a calcium carbonate level near the minimum end if the tolerance, and one with the level at the upper end of the tolerance band. And, it was shown that high levels of calcium carbonate would deposit in the gas tube, in hot humid conditions.
Calcium carbonate is a good erosion preventative, so it was desired that its concentration not be reduced to the low end of the tolerance band, as no fouling problems were noted in the M14, M60 or M73, and it was important to keep the machine guns from eroding their bores. However, it was decided that the 5.56mm should only be loaded with WC846 made with the minimum allowable calcium carbonate. So, WC846 was broken into two separate product lines, WC846 made as it had previously, and the new low calcium carbonate variant WC846 for 5.56mm. Later, the mixture for 5.56mm ammunition was tweaked and split off as WC844
WC846 (P/N 10534784)
Graphite - 0.40%
Sodium Sulphate - 0.50%
Calcium Carbonate - 0.30-0.50% (to be applied as a surface coating)
Nitroglycerin - 8.00-11.00%
Diphenylamine - 0.75-1.50%
Dibutylphthalate - 3.50-7.00%
Nitrocellulose - REMAINDER
WC844T (P/N 9378273) (similar to the low CaCO3 WC846)
Graphite - 0.40%
Sodium Sulphate - 0.50%
Calcium Carbonate - 0.15-0.30% (to be applied as a surface coating)
Nitroglycerin - 8.00-11.00%
Diphenylamine - 0.75-1.50%
Dibutylphthalate - 3.50-7.00%
Nitrocellulose - REMAINDER
WC844 (P/N 10542743)
Nitrocelulose
Graphite
Sodium Sulfate
Calcium Carbonate
Dinitrotoluene
Potassium Nitrate
Tin Dioxide
Nitroglycerine
Diphenylamine
Dibutylphthalate
EDIT: Tin dioxide is a de-coppering agent, dinitrotoluene is a deterrent, and potassium nitrate is a flash reducer.
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