Besides the obvious design criteria like spring rate, appropriate material and process selection are important components to ensure that springs remain functional and prevent relaxation or fatigue.
You will note from the source material cited below that not all spring wire alloys are the same. “Commercial” grade spring wire may be adequate for some applications, but it does not have the same properties that “valve” grade exhibits. The processing necessary and quality control necessary to achieve the consistent surface finish necessary for high-fatigue applications certainly adds to cost. Additional processing like shot peening and stress relief will also provide improved properties at additional cost.
Many of the firearms springs that we are concerned with are not exposed to high temperatures, so better-quality music wire springs may be quite appropriate. Depending upon where in the gun’s mechanism a spring resides and the conditions it is exposed to due to the combustion process or environment (e.g., saltwater), corrosion resistance may or may not be of particular concern. Shooters who swim with their carbines may have different material requirements than those who never leave the high desert.
From the Century Spring Technical FAQ
http://www.centuryspring.com/pdfs/techfaqs.pdf
What material is best for high temperature applications?
As temperature resistance increases, the material and processing cost typically increases significantly. Therefore, it is usually wise to select a material that provides resistance for the intended temperature range with minimal excess capability. The table below lists a variety of spring materials and their maximum service temperatures.
Wire Type / Max Temp.
Music Wire 250°F
Hard Drawn Carbon 250°F
Oil Tempered Carbon 300°F
Chrome Vanadium 425°F
Chrome Silicon 475°F
302 Stainless 500°F
17-7 PH 600°F
NiCr A286 950°F
Inconel 600 700°F
Inconel X750 1100°F
Most spring materials are defined in ASTM specifications. …A list of popular material types and the corresponding ASTM specification is given below.
Wire Type / ASTM Spec
Oil Tempered Carbon (Commercial) A229
Oil Tempered Carbon (Valve) A230
Chrome-Silicon (Commercial) A401
Chrome-Silicon (Valve) A877
Chrome-Vanadium (Commercial) A231
Chrome-Vanadium (Valve) A232
Hard Drawn Carbon A227, A764
High Tensile Hard Drawn Carbon A679
Music Wire A228
Stainless Steel A313
Fatigue Applications:
Since spring wire is primarily subjected to torsional stresses, maximum stress levels occur at the wire surface. As a result, material surface defects (i.e. seams, laps, pits, etc.) can dramatically reduce a spring’s fatigue life. Knowing this, wire manufacturers have developed surface preparation methods to restrict the size of wire surface defects as it leaves the mill. Wire produced with these methods is rated for fatigue applications and is often referred to as “valve spring quality”. Since these methods often involve costly processes, fatigue-rated spring wire is often significantly more expensive than its commercial grade counterpart. The two most popular materials for fatigue applications today are Music Wire (ASTM A228) and Chrome-Silicon Valve Spring Quality (ASTM A877). At wire sizes below approximately 0.080" (2.0 mm), Music Wire offers higher tensile strength; however, Music Wire’s maximum service temperature is less than that of Chrome-Silicon.
Corrosion Resistance:
Once again, the actual operating environment plays a significant role. Many coatings are available that can provide adequate corrosion resistance for wire types that would not themselves resist corrosion. These include powder coating, phosphating with an oil dip or spray, and plating in some cases. Generally speaking, a coated spring produced from a traditional spring material will involve less cost than producing a spring from stainless steel. When the application is such that coated spring wire will not meet the requirements of the application, the focus turns to stainless steel wire. Type 302 stainless steel is generally the first choice. This wire can yield very corrosion-resistant springs for most environments. When the application calls for high operating temperatures as well, 17-7 PH wire will also likely be considered.
From the SAE (Society of Automotive Engineers) Manual on Design and Application of Helical and Spiral Springs, SAE HS-795 :
Shot Peening— This surface treatment has done more to increase the life of springs than any alloy steel or other process ever employed.
Relaxation or Load Loss in Helical Springs at Elevated Temperatures
If a helical spring is compressed by a given amount between parallel plates at elevated temperature, it will be found that the load exerted by the spring will gradually relax or drop off with time. The amount of this relaxation, or set, generally increases as the stress and/or temperature increases. Normally, the set is greater for long periods of time than for short ones.
Common Causes of Spring Failure:
1. Surface Imperfections
2. Corrosion--Corrosion is the major environmental factor which will promote spring breakage. It destroys and removes metal from the surface of the spring by chemical or electrochemical methods in an irregular fashion which causes an overall reduction in the spring stock size, compounded by localized areas of intensive metal removal. These effects seriously reduce both the static strength and the fatigue strength of the spring.
3. Improper Heat Treatment
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