The OP has the right idea here. Test you gear now when you can afford to screw it up so you will get it right when it counts. I was an avid hiker covering all of the AT in PA and adjoining states (I saw "was" b/c now I have little kids and can barely get away for a round of golf let alone a 3-7 day hike!!!). I started with an ALICE pack as well (former military) but eventually switched to the "ultra-light" or minimalist theory of hiking.
So a couple suggestions -
--consider a tarp or specially designed waterproof cover rather than a tent. Usually much lighter, and all you need is some 550 cord and a couple bungies rather than poles, stakes, cord.
--Rinsing pots in streams and lakes is a must, conserve water and they make biodegradable/non-toxic soaps you can use after to be sure it is clean.
--The lighter you pack the lighter boots you can wear (less support needed) and they say a pound on your feet equals at least 5 on your back (or something like that).
There is plenty of other stuff out there including a really good, easy and high calorie meal called "moose goo" that will save you on fuel (eat it cold) and space (very small, packages) and money (you make it at home). This is the website I started ultralight packing at:
http://www.ultralightbackpacker.com/
best of luck and most importantly enjoy the hike....I'm jealous!
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